WebLithium bis(trimethylsilyl)amide is a base used in preparation of dienes and enolates. It is used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to … WebApr 15, 1998 · Semantic Scholar extracted view of "Reaktionen von Bis(trimethylsilyl)amino-substituierten Chlorsilanen [(Me3Si)2N]Me2−nPhnSiCl (n=0, 1, 2) mit Lithium—Darstellung von Bis(trimethylsilyl)amino-substituierten Silyllithiumverbindungen und Disilanen" by I. Rietz et al.
Lithium bis(trimethylsilyl)amide 97 4039-32-1 - Sigma …
WebThe invention provides a process for preparing lithium bis (trimethyldisilyl) amide, which comprises the following steps of: under the protection of inert gas, adding lithium, isoprene, hexamethyldisilazane and tetrahydrofuran into a reaction vessel, carrying out one-step synthesis reaction, and preparing to obtain the finished product. WebLithium bis (trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN (SiMe 3) 2. It is commonly abbreviated as LiHMDS ( Li thium H exa M ethyl D i S ilazide … top 10 big man in the nba all time
Bis(trimethylsilyl)amine - Wikipedia
WebLithium bis(trimethylsilyl)amide (LiHMDS) is a sterically hindered strong base. It is commercially available as a solid and as a solution in a variety of solvents (ex. THF, 2Me … Lithium bis(trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN(Si(CH3)3)2. It is commonly abbreviated as LiHMDS or Li(HMDS) (lithium hexamethyldisilazide - a reference to its conjugate acid HMDS) and is primarily used as a strong non-nucleophilic base and as a ligand. Like many lithium reagents, it has a tendency to aggregate and will form a cyclic trimer in t… WebTris (trimethylsilyl)amine is obtained by reaction of the sodium salt of hexamethyldisilazane - from hexamethyldisilazane and sodium amide [7] or from hexamethyldisilazane, sodium and styrene [1] - with trimethylchlorosilane in 80% yield. [8] top 10 big pharma